论文摘要
A novel heteronuclear metal organic framework（MOF） incorporating both transition and alkali metal ions, namely, {(Ni2K2L2·bipy]×6 H2O]×2 H2O}n（1, L = N-phosphonomethyl amino diacetic acid, bipy = 4,4?-dipyridine） has been obtained. Its structure was established by single-crystal X-ray diffraction analysis and further characterized by elemental analysis and IR spectroscopy. The complex crystallizes in orthorhombic system, space group Pccn with a = 14.650（11）, b = 36.56（3）, c = 7.112（5） ? and V = 3809.3（8） ?3. In this framework, bipy connects adjacent Ni–K heteronuclear coordination units into 1 D railway type chains, which are further propagated into 2 D deck-like array bearing large tunnels through the carboxylic oxygen from N-phosphonomethyl amino diacetic acid. The molar electrical conductivity of heteronuclear complex increases gradually with increasing the temperature. Complex 1 also exhibits strong photoluminescent emission in the visible region.
论文目录
文章来源
类型: 期刊论文
作者: 冯勋,陈海鹏,贾红,马芬,张道铭,李中军
来源: Chinese Journal of Structural Chemistry 2019年04期
年度: 2019
分类: 工程科技Ⅰ辑
专业: 化学
单位: College of Chemistry and Chemical Engineering and Henan Key Laboratory of Function Oriented Porous Materials, Luoyang Normal University,College of Physical and Electronic Information, Luoyang Normal University,College of Chemistry and Molecular Engineering, Zhengzhou University
基金: This project was supported by the National Foundation for Science of China(No.U180411457),Foundation for Science&Technology Innovation Talents in Henan province(No.16410010012),the Foundation of Education Committee of Henan province(No.182102310897)
分类号: O641.4
DOI: 10.14102/j.cnki.0254-5861.2011-2085
页码: 597-604
总页数: 8
文件大小: 818K
下载量: 28
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