论文摘要
The synthesis of sulfur-containing polymer, a very promising functional material, has made a great progress in the past several years. This review is focused on the very recent advances in poly（monothiocarbonate）s derived from carbonyl sulfide（COS） and epoxides including biomass-derived epoxides. Of significance, metal-free catalyst systems, including triethyl borane/Lewis base pair and thiourea/Lewis base pair are developed for the alternating copolymerization of COS with epoxides. Thereof, the thiourea/Lewis base pair is highly active to the copolymerization of COS with epoxide in a living manner. Moreover, a series of crystalline poly（monothiocarbonate）s are presented, including the copolymers derived from COS with oxetane, ethylene oxide, enantiopure epichlorohydrin, and achiral mesoepoxides via enantioselective copolymerization. Based on these COS/epoxide copolymerization process, a variety of COS-based block copolymers with well-defined structure are presented.
论文目录
文章来源
类型: 期刊论文
作者: Cheng-Jian Zhang,Xing-Hong Zhang
来源: Chinese Journal of Polymer Science 2019年10期
年度: 2019
分类: 工程科技Ⅰ辑
专业: 化学
单位: Key Laboratory of Macromolecular Synthesis and Functionalization (Ministry of Education), Department of Polymer Science & Engineering, Zhejiang University
基金: financially supported by the National Natural Science Foundation of China (No. 21774108),the Distinguished Young Investigator Fund of Zhejiang Province (No. LR16B040001)
分类号: O631
页码: 951-958
总页数: 8
文件大小: 692K
下载量: 8
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