Controlling Heat Transfer for the Manufacturing of High Molecular Weight Polyisobutylene via Formation of Micelles

论文摘要

An alternative cationic polymerization method is developed to produce high molecular weight polyisobutylene（HM-PIB） with molecular weights above 5 × 105 g/mol. The method involves micelle formation via functionalized low molecular weight polyisobutylene（LM-PIB） in non-polar solvent. One end of LM-PIB is modified with an imidazolium-containing ionic group, which together with the anion（e.g. Al2Cl7） works as Lewis acid. While the monomer isobutylene dissolves readily in non-polar solvent, polymerization can occur only within the micelle, which affords stable HM-PIB particles. HM-PIB with a molecular weight（MW） close to 1 × 106 g/mol was produced successfully with the described method.

论文目录

文章来源

类型: 期刊论文

作者: Szilard Csihony,Nicole Janssen,Klaus Mühlbach

来源: Chinese Journal of Polymer Science 2019年09期

年度: 2019

分类: 工程科技Ⅰ辑

专业: 化学

单位: Advanced Materials & Systems

分类号: O613

页码: 898-902

总页数: 5

文件大小: 554K

下载量: 7

相关论文文献

• [1].Lewis pairs polymerization of polar vinyl monomers[J]. Science Bulletin 2019(24)
• [2].A personal journey on using polymerization in aqueous dispersed media to synthesize polymers with branched structures[J]. Chinese Chemical Letters 2019(12)
• [3].Synergetic organocatalysis for stereoregular ring-opening polymerization of O-carboxyanhydrides to isotactic functionalized polyesters[J]. 材料导报 2020(12)
• [4].Analysis and research on the processing threshold of femtosecond laser[J]. Optoelectronics Letters 2020(05)
• [5].Neodymium Organic Sulfonate Complexes: Tunable Electronegativity/Steric Hindrance and Application in Controlled Cis-1,4-polymerization of Butadiene[J]. Chinese Journal of Polymer Science 2019(03)
• [6].Organocatalytic polymerization[J]. Science China(Chemistry) 2019(09)
• [7].In situ molecular level visualization of RAFT polymerization by AIEgen-labelled agents[J]. Science China(Chemistry) 2018(10)
• [8].Topochemical polymerization of diphenyldiacetylene-based materials and the relevant application in photocatalysis[J]. Chinese Chemical Letters 2018(11)
• [9].Controlled Radical Polymerization of Styrene Mediated by Xanthene-9-thione and Its Derivatives[J]. Chinese Journal of Polymer Science 2018(12)
• [10].Two-photon polymerization fabrication and Raman spectroscopy research of SU-8 photoresist using the femtosecond laser[J]. Optoelectronics Letters 2017(03)
• [11].Progress on intelligent hydrogels based on RAFT polymerization:Design strategy, fabrication and the applications for controlled drug delivery[J]. Chinese Chemical Letters 2020(01)
• [12].Combination of olefin insertion polymerization and olefin metathesis to extend the topology and composition of polyolefins[J]. Science China(Chemistry) 2020(06)
• [13].Step-growth polymerization of traptavidin-DNA conjugates for plasmonic nanostructures[J]. Chinese Chemical Letters 2020(05)
• [14].Self-assisted stereospecific polymerization of unmasked polar 4-methylthio-1-butene[J]. Science China(Chemistry) 2019(06)
• [15].Hydrophobic coating of surfaces by plasma polymerization in an RF plasma reactor with an outer planar electrode: synthesis,characterization and biocompatibility[J]. Plasma Science and Technology 2017(08)
• [16].Facile Synthesis of High Molecular Weight Polypeptides via Fast and Moisture Insensitive Polymerization of α-Amino Acid N-Carboxyanhydrides[J]. Chinese Journal of Polymer Science 2020(10)
• [17].Electrochemical polymerization of 2,6-pyridinediamine and characterization of the resulting polymer[J]. Chinese Chemical Letters 2012(11)
• [18].Relationship between polymerization degree and cementitious activity of iron ore tailings[J]. International Journal of Minerals Metallurgy and Materials 2010(01)
• [19].Preparation of nano-compounded polyolefin materials through in situ polymerization technique:status quo and future prospects[J]. Chinese Science Bulletin 2009(01)
• [20].Correlation between ~(29)Si polymerization and cementitious activity of coal gangue[J]. Journal of Zhejiang University(Science A:An International Applied Physics & Engineering Journal) 2009(09)
• [21].Room temperature polymerization of alkyl isocyanates catalyzed by rare earth Schiff base complexes[J]. Science in China(Series B:Chemistry) 2009(11)
• [22].Studies on the Structures and Spectra of Benzothiophene Oligomers[J]. 结构化学 2008(04)
• [23].Dynamic Monte Carlo Simulation on Polymerization of Encapsulant[J]. Chinese Journal of Polymer Science 2019(02)
• [24].Lewis acid/base modulation in β-diiminate zinc-catalyzed switchable ring-opening polymerization of rac-lactide[J]. Science China(Chemistry) 2019(04)
• [25].Pressure-induced polymerization of butyndioic acid and its Li~+ salt[J]. Chinese Chemical Letters 2018(02)
• [26].Polyaniline-based electrocatalysts through emulsion polymerization:Electrochemical and electrocatalytic performances[J]. Journal of Energy Chemistry 2017(01)
• [27].Polyaniline nanostructures tuning with oxidants in interfacial polymerization system[J]. Progress in Natural Science:Materials International 2015(05)
• [28].Anionic polymerization of fluorine-substituted phenyl methacrylates[J]. Science China(Chemistry) 2015(01)
• [29].Stereoblock Polypropylenes Prepared by Efficient Chain Shuttling Polymerization of Propylene with Binary Zirconium Catalysts and iBu_3Al[J]. Chinese Journal of Polymer Science 2020(11)
• [30].Catalytic synthesis of perfluorolyethers[J]. Journal of Central South University 2013(03)