论文摘要
We report herein an efficient catalytic epoxidation reaction for the synthesis of epoxyketone（tert-butyl（（S）-4-methyl-1-（（R）-2-methyloxiran-2-yl）-1-oxopentan-2-yl）carbamate）, which is an important synthetic intermediate of carfilzomib. A series of bioinspired manganese complexes bearing N4 ligands are carefully investigated in the epoxidation of enone precursor with H2O2 as oxidant in the presence of carboxylic acid（e.g., acetic acid）.
论文目录
文章来源
类型: 期刊论文
作者: Bin Qiu,Chungu Xia,Wei Sun
来源: Chinese Chemical Letters 2019年03期
年度: 2019
分类: 工程科技Ⅰ辑
专业: 有机化工
单位: Key Laboratory for Oxo Synthesis and Selective Oxidation, Suzhou Research Institute of LICP, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences,University of Chinese Academy of Sciences
基金: financial support of this work from the National Natural Science Foundation of China (No. 21473226),Key Research Program of Frontier Sciences,CAS(No. QYZDJ-SSWSLH051),Natural Science Foundation of Jiangsu Province (Nos. BK20161261 and BK20170420)
分类号: TQ460.1
页码: 698-701
总页数: 4
文件大小: 401K
下载量: 3
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