论文摘要
Three stable coordination polymers（CPs） assembled by 3,5-（carboxybenzyloxy）-benzoic acid（H3 L） and 1,10-phenanthroline（phen）, namely, [Zn（HL）（phen）]n（1）, [Cd（HL）（phen）]n（2） and [Co（HL）（phen）]n（3）, have been synthesized under hydrothermal conditions. Their structures have been determined by single-crystal X-ray diffraction analyses and further characterized by elemental analyses, infrared（IR） spectroscopy and powder X-ray diffraction（PXRD）. Investigation on crystal structure indicates that complexes 1 ～ 3 exhibit similar architecture. In these complexes, metal ions coordinate with H3 L and phen ligands, forming infinite 1 D chains. Then the adjacent chains combine together through intramolecular hydrogen-bonding interactions, generating 2 D supramolecular architectures. In addition, complexes 1～3 present excellent thermal stabilities and 1 and 2 exhibit strong luminescent emission bands at room temperature.
论文目录
文章来源
类型: 期刊论文
作者: 刘力辉,王炫博,刘博,乔宇,姜维,车广波,刘春波
来源: Chinese Journal of Structural Chemistry 2019年06期
年度: 2019
分类: 工程科技Ⅰ辑
专业: 化学
单位: Institute of Green Chemistry and Chemical Technology, Jiangsu University,Key Laboratory of Preparation and Application of Environmental Friendly Materials (Jilin Normal University), Ministry of Education,College of Environmental Science and Engineering, Jilin Normal University
基金: Supported by the NNSFC(No.21576112),NSF of Jilin Province(20180623042TC,20180101181JC,20150623024TC-19),the Project of Education Department of Jilin Province(JJKH20180775KJ),the Project of Human Resources and Social Security Department of Jilin Province(2017956),the Opening Project of Key Laboratory of Polyoxometalate Science of Ministry of Education
分类号: O641.4
DOI: 10.14102/j.cnki.0254-5861.2011-2169
页码: 947-955
总页数: 9
文件大小: 1850K
下载量: 27