Low-molecular-weight photoresponsive supramulecular hydrogel based on a dicationic azobenzene-bridged pyridinium hydrogelator

Low-molecular-weight photoresponsive supramulecular hydrogel based on a dicationic azobenzene-bridged pyridinium hydrogelator

论文摘要

Low-molecular-weight supramolecular hydrogels are of significant attractive soft materials as particular functions can be facilely introduced by the straightforward fabrication of such self-assembled systems. In this study, an azobenzene-bridged dicationic pyridinium salt was synthesized, from which photoresponsive supramolecular hydrogel could be fabricated through the π-π stacking and hydrophobic interactions in the aqueous solution. By taking advantages of the UV-vis light induced E/Z photoisomerization behaviors of the incorporated azobenzene photochromophore, reversible gel-sol transformation of such supramolecular hydrogel could be achieved under the alternating UV-vis irradiation conditions. We believed that this photoresponsive supramolecular hydrogel will be a good supplementary in the creation of intelligent soft material.

论文目录

文章来源

类型: 期刊论文

作者: Si-Tai Zheng,Huan-Huan Yin,Zhao-Guang Ma,Nan-Li Sheng,Tian-Guang Zhan,Xiao-Yang Yan,Jiecheng Cui,Li-Juan Liu,Kang-Da Zhang

来源: Chinese Chemical Letters 2019年03期

年度: 2019

分类: 工程科技Ⅰ辑

专业: 化学

单位: Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, College of Chemistry and Life Science, Zhejiang Normal University,Xingzhi College of Zhejiang Normal University

基金: the National Natural Science Foundation of China (Nos. 21502216 and 21602205),Natural Science Foundation of Zhejiang Province (No. LQ19B020019) for the financial support to this research

分类号: O648.17

页码: 707-709

总页数: 3

文件大小: 572K

下载量: 7

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Low-molecular-weight photoresponsive supramulecular hydrogel based on a dicationic azobenzene-bridged pyridinium hydrogelator
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